Magnetic tapes are extensively used for recording audio and video signals, although it is unclear how long this technology will continue to be used with the rising popularity of the digital versatile disk (DVD).
Tapes can be made with either a particulate media adhered to a plastic substrate or a metal evaporated (ME) film on the substrate. The magnetic layer on a particulate tape is only 40% magnetic material whereas ME tapes have a 100% magnetic layer. Therefore, ME tapes give better quality recording, but they are more time consuming to produce and are more expensive. Particulate tapes are much cheaper and hence account for the majority of magnetic tapes.
There is a range of magnetic particulates that can be used for tapes and these are listed in table 5, with their magnetic properties. The values of coercivity quoted in table 4 are approximate averages as the coercivity is highly dependent on particle size and shape, which will vary in any batch of powder.
Smaller particle size and higher magnetisation lead to better quality recording, i.e. greater signal to noise ratio. As the density of recording increases then the magnetic domain size decreases and so the particle size must decrease and the coercivity of the material must increase.
The cheapest and most commonly used material is g-Fe2O3, while increasing quality is achieved through the use of cobalt modified (2-3wt%) g-Fe2O3, chromium dioxide and, the best, pure iron.
Finally, also mentioned in table 5, is barium hexaferrite, which has the highest coercivity and is used for applications where the stored data must be secure and is unlikely to require rewriting, e.g. a credit card.
|
Material
|
Saturation Polarisation (mT)
|
Intrinsic Coercivity (kAm-1)
|
Average Particle Size (mm)
|
Particle Shape
|
|
y-Fe2O3
|
440
|
30
|
0.5 x 0.1
|
Needle
|
|
Co modified y-Fe2O3
|
460
|
60
|
0.5 x 0.1
|
Needle
|
|
CrO2
|
600
|
70
|
0.4 x 0.05
|
Needle
|
|
Fe
|
2100
|
125
|
0.15 x 0.05
|
Needle
|
|
BaO.6Fe2O3
|
460
|
200
|
0.15 x 0.05
|
Disc
|
The production route for a particulate magnetic tape is illustrated in figure 15. The magnetic particles are mixed with a binder (dissolved in a solvent), lubricants that will help reduce the friction when then tape is moved over the head and abrasives (such as Al2O3) that are hard and help prevent wear of the magnetic tape.
This mixture is poured onto a PET (polyethylene tetraphthalate) substrate, which is ~25mm thick. Sometimes aramid substrates are used for long play cassettes, as these substrates can be as thin as 5mm.
The particles are magnetically anisotropic, usually due to their shape, and the next stage of the process is to align these particles in the length of the tape while the magnetic layer is still liquid. The solvent is then evaporated by heating the tape and it is rolled to improve the density and leave a magnetic layer of about 3-5mm thick.
Figure 15: The processing route for particulate magnetic tape.