Dr Phoebe Allan MSci, PhD

Image courtesy - Diamond Light Source

School of Chemistry
Associate Professor in Materials Chemistry
Birmingham Fellow

Contact details

Address
School of Chemistry
Haworth Building
University of Birmingham
Edgbaston
Birmingham
B15 2TT

Dr Phoebe Allan is a Associate Professor in the School of Chemistry.

Her research focuses on materials chemistry for energy storage. The goal of her research is to understand the links between the structure of a material, and its electrochemical properties, using techniques including: synchrotron X-ray and neutron powder diffraction, pair distribution function analysis, and spectroscopic techniques (Raman, NMR, X-ray adsorption spectroscopy). A particular interest is developing experiments which probe the structure of a material as it changes, in real-time, and under operational conditions. This approach gives insight into which structural features are desirable for obtaining new materials with improved performance.

Current areas of interest include new electrode and electrolyte materials for lithium- and sodium- and aluminium-ion batteries.

Qualifications

  • PhD in Chemistry, University of St Andrews, 2012
  • MSci Natural Sciences (Physical), University of Cambridge, 2008

Biography

Dr Allan studied Physical Natural Sciences at the University of Cambridge from 2004 - 2008.  Her final year project focused on the synthesis and characterisation of metal-organic frameworks using phosphine-based ligands, under the supervision of Dr Simon Humphrey. 

She completed a PhD with Professor Russell Morris FRS at the University of St Andrews in 2012, where she worked on the storage of medical gases using metal-organic frameworks. She was a Post-Doctoral Research Fellow in the group of Professor Clare Grey FRS from 2012 – 2013, then held a Junior Research Fellow at Gonville and Caius College, and an Oppenheimer Fellowship from the School of Physical Sciences, University of Cambridge from 2013 – 2018. Here, her research focused on developing synchrotron-based studies to understand and develop new electrodes for lithium and sodium-ion batteries.

From 2015 – 2017, she has also worked as a beamline support scientist at Diamond Light Source -  the UK’s synchrotron source, developing sample environments for diffraction and imaging beamlines, and later working on the design of the new Dual Imaging and Diffraction (DIAD) beamline which became operational in 2020. 

Postgraduate supervision

Phoebe is seeking motivated students for projects in the following areas:

  • Synthesis and characterisation of new potential electrode materials for sodium- and aluminium-ion batteries
  • Developing synchrotron-based methods for understanding synthesis-structure-property relationships in energy materials.

If you are interested in studying one of these subject areas, please contact Dr Allan on the contact details above, or for any general doctoral research enquiries, please email: dr@contacts.bham.ac.uk

For a full list of available Doctoral Research opportunities, please visit our Doctoral Research programme listings.

Research

Research Themes:

  • Solid-state electrochemistry
  • Lithium- and sodium-ion batteries
  • Diffraction and spectroscopy
  • Crystallography

Publications

Selected publications:

  • Stratford, J. M., Kleppe, A. K., Keeble, D. S., Chater, P. A., Meysami, S. Wright, C. J., Barker, J., Titirici, M-M., Allan, P. K., Grey, C. P., Correlating Local Structure and Sodium Storage in Hard Carbon Anodes: Insights from Pair Distribution Function Analysis and Solid-State NMR, Journal of the American Chemical Society (2021), 143 (35), 14274
  • Hua, X., Allan, P. K., Gong, C., Chater, P. A., Schmidt, E. M., Geddes, H. S., Robertson, A. W., Bruce, P. G. and Goodwin, A. L., Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries, Nature Communications (2021), 12, 561
  • Diaz-Lopez, M., Cutts, G. L., Allan, P. K., Keeble, D. S., Ross, A., Pralong, V., Spiekermann, G., Chater, P. A., Fast operando X-ray pair distribution function using the DRIX electrochemical cell, Journal of Synchrotron Radiation (2020), 27, 1190
  • Tsiamtsouri, M. A., Allan, P. K., Pell, A. J., Stratford, J. M., Kim, G., Kerber, R. N., Magusin, P. C. M. M., Jefferson, D. A., Grey, C. P., Exfoliation of Layered Na-Ion Anode Material Na2Ti3O7 for Enhanced Capacity and Cyclability, Chemistry of Materials (2018), 30, (5) 1505
  • Stratford, J. M., Mayo, M., Allan, P. K., Pecher, O., Borkiewicz, O. J, Wiaderek, K. M., Chapman, K. W., Pickard,C. J., Morris, A. J., Grey, C. P., (2017) Investigating Sodium Storage Mechanisms in Tin Anodes: A Combined Pair Distribution Function Analysis, Density Functional Theory and Solid-State NMR Approach, Journal of the American Chemical Society, (2017), 139 (21), 7273
  • Stratford, J. M., Allan, P. K., Pecher, O., Chater, P. A, Grey, C. P., Mechanistic insights into sodium storage in hard carbon anodes using local structure probes, Chemical Communications (2016), 52, 12430 

View all publications in research portal